Franck-Condon integral for bound-free transitions between harmonic and flat potentials using exact wavefunctions

Autor:	J. R. Wiesenfeld, S.M. Adler
Rok vydání:	1977
Předmět:	Physics Atomic electron transition Quantum mechanics Semiclassical physics Harmonic (mathematics) Orbital overlap Function (mathematics) Physical and Theoretical Chemistry Wave function Spectroscopy Atomic and Molecular Physics and Optics WKB approximation Harmonic oscillator
Zdroj:	Journal of Molecular Spectroscopy. 66:357-367
ISSN:	0022-2852
Popis:	The spectral features of electronic transitions between a bound upper state and a relatively flat lower state may be modeled using harmonic oscillator and particle-in-a-box wavefunctions. Evaluation of the Franck-Condon overlap integral yields an expression for the spectral intensity as a function of transition energy which displays the characteristic broad and narrow fluctuations. The very good agreement between these results and those obtained from a semiclassical WKB treatment supports the applicability of the WKB method to problems involving realistic potentials.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bde1629ca165274f5369129185526ba7 https://doi.org/10.1016/0022-2852(77)90294-6 Zobrazit plný text záznamu