Synthesis and structural characterization of a novel diosmium(III) compound: Os2(ap)4Cl2

Autor:	Judith L. Eglin, Guo-Lin Xu, Tong Ren, Damon A. Parrish, Martin H. Moore, Wei-Zhong Chen, Alfred P. Sattelberger, Steven K. Pollack, R. Shashidhar, Jeffrey R. Deschamps, Terence L. Schull
Rok vydání:	2004
Předmět:	Inorganic Chemistry Bond length Diffraction Crystallography Stereochemistry Chemistry Materials Chemistry Molecule Crystal structure Physical and Theoretical Chemistry Electrochemistry Single crystal Characterization (materials science)
Zdroj:	Inorganica Chimica Acta. 357:1313-1316
ISSN:	0020-1693
DOI:	10.1016/j.ica.2003.09.021
Popis:	The reaction between Os 2 (OAc) 4 Cl 2 and H ap (H ap is 2-anilinopyridine) under prolonged refluxing conditions resulted in a new Os 2 (III) compound, Os 2 ( ap ) 4 Cl 2 ( 1 ). The molecular structure of 1 was determined from a single crystal X-ray diffraction study, which revealed an Os–Os bond length of 2.396[1] A, and a cis- (2,2) arrangement of the ap ligands. Also reported are magnetic, electrochemical and spectroscopic properties of 1 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bdce6bd41ee00682d364079917036e0f https://doi.org/10.1016/j.ica.2003.09.021 Zobrazit plný text záznamu Full Text from ScienceDirect