An Appraisal of Hydrocarbons Conversion Reactions During Naphtha Reforming Process
Autor: | Syed A. Ali, Mohammed Ali, Mohammed Abdul Bari Siddiqui |
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Rok vydání: | 2007 |
Předmět: |
chemistry.chemical_classification
General Chemical Engineering Energy Engineering and Power Technology chemistry.chemical_element General Chemistry Geotechnical Engineering and Engineering Geology Catalysis Cracking Fuel Technology Pilot plant Hydrocarbon chemistry Organic chemistry Dehydrogenation Selectivity Carbon Naphtha |
Zdroj: | Petroleum Science and Technology. 25:1321-1331 |
ISSN: | 1532-2459 1091-6466 |
DOI: | 10.1080/10916460701428847 |
Popis: | A pilot plant study was performed to understand the reforming reactions network using a blend of straight run and hydrocracked naphtha. Three major classes of reactions that occurred during reforming were naphthenes dehydrogenation, n-paraffins cracking, and dehydrocyclization. The increase in aromatics was attributed to paraffin dehydrocyclization, the selectivity of which increases with carbon number. Aromatic contents were increased, while other hydrocarbons were decreased and converted to aromatics. Naphthenes were converted to aromatics of the same carbon number. The results indicated a drop in aromatic content as the catalyst deactivated with an increase in time on stream. |
Databáze: | OpenAIRE |
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