Asymmetric organocatalytic reactions of o-hydroxycinnamaldehydes with organoboronic acids: a facile enantioselective access to chromanes and dihydrobenzopyranes

Autor: Sung-Gon Kim, Kwang‐Su Choi
Rok vydání: 2010
Předmět:
Zdroj: Tetrahedron Letters. 51:5203-5206
ISSN: 0040-4039
Popis: Catalytic asymmetric 1,4-addition reactions of organoboronic acids to o-hydroxycinnamaldehydes, which afford chromanes and dihydrobenzopyranes, have been established using an organocatalyst derived from imidazolidinone. The chromanes have been obtained in high chemical yields and enantioselectivities and can be readily used to obtain a variety of chromane derivatives through subsequent transformations.
Databáze: OpenAIRE