ChemInform Abstract: (1-Ethoxyvinyl)lithium in the Total Synthesis of Thymine Polyoxin C and Uracil Polyoxin C

Autor:	Kimio Uchida, Keisuke Kato, Cheng Yu Chen, Hiroyuki Akita
Rok vydání:	2010
Předmět:	chemistry.chemical_compound chemistry Pyrimidine Stereochemistry Nucleic acid Polyoxin C Total synthesis chemistry.chemical_element Lithium General Medicine Uracil polyoxin C Thymine
Zdroj:	ChemInform. 29
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.199848252
Popis:	A short path synthesis of the ethyl (methyl 2, 3-O-isopropylidene-β-D-allofuranosid)uronate (5) and ethyl(methyl 2, 3-O-isopropylidene-α-L-talofuranosid)uronate (6) from methyl 2, 3-O-isopropylidene-β-D-ribopentodialdo-1, 4-furanoside (3) using (1-ethoxyvinyl)lithium and its application to the total synthesis of the pyrimidine nucleosides, thymine polyoxin C (1) and uracil polyoxin C (2), are described.
Databáze:	OpenAIRE
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