Direct observation of denitrogenation process of 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives, using a visible 5-fs pulse laser

Autor:	Kotaro Okamura, Takayoshi Kobayashi, Shingo Yagi, Manabu Abe, Izumi Iwakura, Jun Liu, Atsushi Yabushita
Rok vydání:	2012
Předmět:	Chemistry Stereochemistry Direct observation General Physics and Astronomy Physical and Theoretical Chemistry Photochemistry Ene reaction Pulsed laser deposition
Zdroj:	Chemical Physics Letters. 527:79-83
ISSN:	0009-2614
Popis:	The mechanism of denitrogenation for 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives was investigated using a visible 5-fs pulse laser. The time-dependent wavenumber changes observed in this study revealed that the concerted denitrogenation occurs in the parent DBH. However, a stepwise denitrogenation mechanism was found for the 7,7-diethoxy-substituted DBH derivative.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bda7403cd0ed1a9c32da12f070375e5a https://doi.org/10.1016/j.cplett.2012.01.024 Zobrazit plný text záznamu Full Text from ScienceDirect