Xanthouroleuconaphin: a yellowish pigment from the aphid Uroleucon nigrotuberculatum and its total synthesis

Autor:	Tetsuto Tsunoda, Masami Tanaka, Ayaka Sogabe, Takeshi Nishii, Taichi Nishimura, Hiroto Kaku, Makoto Inai, Shigeru Takahashi, Kouji Yamada, Mitsuyo Horikawa
Rok vydání:	2013
Předmět:	Aphid biology Fries rearrangement Chemistry Organic Chemistry Total synthesis biology.organism_classification Biochemistry Uroleucon nigrotuberculatum Pigment visual_art Drug Discovery visual_art.visual_art_medium Organic chemistry Two-dimensional nuclear magnetic resonance spectroscopy
Zdroj:	Tetrahedron. 69:1808-1814
ISSN:	0040-4020
DOI:	10.1016/j.tet.2012.12.070
Popis:	A novel yellowish pigment, xanthouroleuconaphin, was isolated from the aphid Uroleucon nigrotuberculatum. Its structure was established by detailed analyses of 1D and 2D NMR spectra and EI-HRMS. Furthermore, the total synthesis of (±)-xanthouroleuconaphin was accomplished via oxidative phenolic coupling of 6-hydroxymusizin, which was prepared by the Fries rearrangement using BF3·2AcOH complex.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bd98b643122aa09f59dee68b51d01f52 https://doi.org/10.1016/j.tet.2012.12.070 Zobrazit plný text záznamu Full Text from ScienceDirect