Studies leading to the large scale synthesis of polyesters using enzymes
| Autor: | Paul Harffey, Stanley M. Roberts, Alan H. Taylor, Falmai Binns |
|---|---|
| Rok vydání: | 1999 |
| Předmět: |
Adipic acid
Condensation polymer integumentary system biology organic chemicals Butane biology.organism_classification Pentane Polyester chemistry.chemical_compound chemistry Propane polycyclic compounds biology.protein Organic chemistry heterocyclic compounds Candida antarctica Lipase hormones hormone substitutes and hormone antagonists |
| Zdroj: | Journal of the Chemical Society, Perkin Transactions 1. :2671-2676 |
| ISSN: | 1364-5463 0300-922X |
| DOI: | 10.1039/a904889h |
| Popis: | The ability of immobilised Candida antarctica lipase to catalyse the condensation of diols and diacids was studied. The range of acids investigated (in condensations with butane-1,4-diol) included adipic, maleic, fumaric, itaconic, (E)-hex-3-enedioic and acetylenedicarboxylic acids, while the diols studied, in condensations with adipic acid, encompassed ethane-, propane-, butane-, pentane- and hexane-diols as well as (Z)-but-2-ene-1,4-diol and but-2-yne-1,4-diol. The oligomerization of hexane-1,6-diol and adipic acid was most facile and was chosen for scale-up. A mechanism for the polycondensation process is proposed. |
| Databáze: | OpenAIRE |
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