Bis[N-benzoyl-N'-(2-pyridylmethylene)hydrazine]trinitratocerium(III) acetone dihydrate

Autor:	D. G. Paschalidis, I. A. Tossidis, P. C. Christidis
Rok vydání:	1999
Předmět:	chemistry.chemical_compound Denticity chemistry Stereochemistry Hydrazine Acetone Molecule General Medicine Crystal structure Hydrate Medicinal chemistry General Biochemistry Genetics and Molecular Biology
Zdroj:	Acta Crystallographica Section C Crystal Structure Communications. 55:707-710
ISSN:	0108-2701
DOI:	10.1107/s0108270199000438
Popis:	The crystal structure of the title compound, [Ce(NO 3 ) 3 -(C 13 H 11 N 3 O) 2 ]. C3 H 6 O.2H 2 O, has been determined. The Ce III atom is 12-coordinate by linking to two tridentate 2-pyridinecarboxaldehyde benzoylhydrazone ligands and three bidentate nitrate ligands. The Ce-O distances range between 2.528 (3) and 2.759 (4) A, and the Ce-N distances range between 2.725 (4) and 2.848 (4) A. All the water molecules are involved in hydrogen-bond formation with the Ce-containing molecules.
Databáze:	OpenAIRE
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