Ultrastable and colorful afterglow from organic luminophores in amorphous nanocomposites: advanced anti-counterfeiting and in vivo imaging application
Autor: | Dan Ding, Qiuqin Huang, Qidan Ling, Zhenghuan Lin, Heqi Gao, Shuming Yang |
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Rok vydání: | 2020 |
Předmět: |
Materials science
Nanocomposite Aryl Nanotechnology 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences Nanomaterials Afterglow Amorphous solid chemistry.chemical_compound chemistry Covalent bond Luminophore General Materials Science Electrical and Electronic Engineering 0210 nano-technology Phosphorescence |
Zdroj: | Nano Research. 13:1035-1043 |
ISSN: | 1998-0000 1998-0124 |
Popis: | Special attention has been paid to the organic afterglow materials (OAM) for their fascinating properties. However, poor stability at air and complicated structure design hinder the development of OAM. Herein, sol-gel, a facile and simple technique, is employed to synthesize a series of organic/inorganic hybrid nanocomposites (N1/SiO2, N2/SiO2, and N3/SiO2) by covalently linking three common aryl imides with crosslinked silica skeleton. These nanomaterials show excitation wavelength-dependent and colorful (yellow, red and green) afterglow of organic imides with long lifetime up to 1.1 s at air. Interestingly, the ultralong phosphorescence is ultrastable under various conditions: water, high temperature, UV irradiation and in vivo, due to the protection of inorganic silica. In particularly, heating to 500 °C does not quench the afterglow of organic luminophore in nanocomposites, but forms new ultralong phosphorescence originated from space-conjugation of silica and carbonyl. The afterglow nanomaterials display huge advantages in the applications of advanced anti-counterfeiting and bioimaging. |
Databáze: | OpenAIRE |
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