Dimethyl ether to olefins conversion in a slurry reactor: Effects of the size of particles and the textural and acidic properties of the MFI-type zeolite
| Autor: | V. S. Pavlov, N. N. Ezhova, N. V. Kolesnichenko, O. V. Yashina, S. V. Konnov, S. N. Khadzhiev |
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| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Chemistry General Chemical Engineering Dispersity Inorganic chemistry Energy Engineering and Power Technology Fraction (chemistry) General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis chemistry.chemical_compound Fuel Technology Geochemistry and Petrology Yield (chemistry) Slurry reactor Dimethyl ether Particle size Zeolite |
| Zdroj: | Petroleum Chemistry. 57:576-583 |
| ISSN: | 1555-6239 0965-5441 |
| DOI: | 10.1134/s0965544117070052 |
| Popis: | Effects of the particle size of a suspended zeolite catalyst based on the commercial MFI-type (high modulus zeolite, HMZ) zeolite on its physicochemical characteristics and catalytic properties in the conversion of dimethyl ether (DME) in a three-phase system with a slurry reactor are studied. In order to gain insight into the relationships between the physicochemical characteristics of MFI-type zeolites and their catalytic properties, the textural, acidic, and catalytic properties of HMZ zeolites and synthesized nanocrystallites of the zeolite with the MFI structure are compared. It was found that, in the conversion of DME in the slurry reactor, the catalytic properties of the MFI zeolite are strongly affected by the size of particles of the suspended catalyst: on passage to nanosized suspensions, the activity of the catalyst grows by several times. Reduction in the size of catalyst particles leads to an increase in the yield of hydrocarbons C5 + and a decrease in the yield of lower olefins. At the same dispersity of suspensions, the catalytic properties of suspended catalysts are considerably affected by the distribution of acid sites over strength in the studied zeolite sample and the fraction of amphoteric sites in them. |
| Databáze: | OpenAIRE |
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