Application of reductive, single electron transfer processes to the generation and cyclization of ω-unsaturated α-amino radicals

Autor:	Stephen F. Martin, William L. Laswell, Heinrich Rüeger, Chih Ping Yang
Rok vydání:	1988
Předmět:	Chemistry Radical Camphorsulfonic acid Organic Chemistry Iminium Photochemistry Biochemistry Metal Single electron chemistry.chemical_compound Samarium diiodide visual_art Drug Discovery Polymer chemistry visual_art.visual_art_medium Dissolution
Zdroj:	Tetrahedron Letters. 29:6685-6687
ISSN:	0040-4039
Popis:	Subjection of ω-unsaturated iminium salts 1 to dissolving metal reduction with samarium diiodide in the presence of camphorsulfonic acid afforded the corresponding α-amino radicals 2 , which underwent facile cyclization via a 5 - exo mode of closure leading to heterocyclic products of the general type 4 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bd35cc21de9c300c4736d0a3e08c172f https://doi.org/10.1016/s0040-4039(00)82428-4 Zobrazit plný text záznamu