A Newμ-Oxo Dimer Iron(III) Complex: Synthesis, Characterization, and Electrocatalysis

Autor:	Jing Wang, Rui-Rui Zhuang, Fangfang Jian, Yuan-Biao Qiao
Rok vydání:	2012
Předmět:	Stereochemistry Dimer chemistry.chemical_element Crystal structure Electrocatalyst Electrochemistry Oxygen Inorganic Chemistry Crystallography chemistry.chemical_compound chemistry Atom Electrode Physical and Theoretical Chemistry
Zdroj:	Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 42:711-715
ISSN:	1553-3182 1553-3174
DOI:	10.1080/15533174.2011.615779
Popis:	A new μ-oxo-bridge diiron (III) complex of [Fe2(μ-O)(Salen)4]·2py 1 (salen = N,N’-ethylene-bis(salicylaldiminato)) was synthesized and characterized by physicochemical and spectroscopic methods. X-ray crystal structure revealed that the homogenous five-coordinated square-based pyramidal diiron species contained two N atoms and two O atoms in the basal positions, whereas the axial position was occupied by O atom, bridging two parent iron atoms. Electrochemical behaviors of the complex in DMF were investigated on silver electrodes, and the possible mechanism of the electrocatalytic reduction of oxygen was proposed
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bd22cd70f0f8dd6acc5c5b423d166a8f https://doi.org/10.1080/15533174.2011.615779 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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