Covalently Functionalized Nanoparticles of Semiconducting Metal Chalcogenides and Their Attributes
| Autor: | Swapan K. Pati, Arkamita Bandyopadhyay, Manaswee Barua, Parvin Fatahi, Pratap Vishnoi, C. N. R. Rao |
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| Rok vydání: | 2017 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Chalcogenide Inorganic chemistry Energy Engineering and Power Technology Nanoparticle Halide Nanotechnology 02 engineering and technology Electronic structure 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Biomaterials chemistry.chemical_compound Förster resonance energy transfer Iodobenzenes chemistry Covalent bond Materials Chemistry Surface modification 0210 nano-technology |
| Zdroj: | ChemNanoMat. 4:41-45 |
| ISSN: | 2199-692X |
| DOI: | 10.1002/cnma.201700252 |
| Popis: | It has been possible to covalently functionalize the semiconducting chalcogenide nanoparticles, ZnS, ZnSe and CdS, by reaction with organic halides, specifically iodobenzenes. DFT calculations have thrown light on the electronic structure of the functionalized chalcogenides. Chalcogenides with bonded phenyl groups exhibit a long wavelength charge-transfer band as predicted by theory. Functionalization has been carried out with fluorophores as well. Functionalization of semiconducting chalcogenide particles offers many possibilities for study of their properties and application. |
| Databáze: | OpenAIRE |
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