The crystal structure of bis(5-chlorosalicylaldoximato)copper(II)

Autor:	E. C. Lingafelter, P. L. Orioli, B. W. Brown
Rok vydání:	1964
Předmět:	Diffraction Materials science Close-packing of equal spheres chemistry.chemical_element Crystal structure Copper Planarity testing Ion Crystallography chemistry Octahedron General Earth and Planetary Sciences Molecule General Environmental Science
Zdroj:	Acta Crystallographica. 17:1113-1118
ISSN:	0365-110X
DOI:	10.1107/s0365110x64002912
Popis:	The crystal structure of bis-(5-chlorosalicylaldoximato)-copper(II), [OCGH3(C1)CHNOH]2Cu, has been determined from partial three-dimensional X-ray diffraction data, hO1 through h21. The cell has dimensions a=13-38, b=3.84, c=7-31 A, a = 8 1 ° 30', fl--98 ° 3', y = 9 8 ° 3', space group P1, and contains one molecule. The copper(II) ion has a distorted octahedral coordination, with Cu-N = 1.96, Cu-O = 1.91 and 3.01 I . The molecule shows considerable deviation from complete planarity. The chlorine atoms form layers with a distorted hexagonal close packing.
Databáze:	OpenAIRE
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