Contribution a l'etude des metaux asymetriques III. Creation, en serie du cymantrene, d'une activite optique inherente a la chiralite du manganese
| Autor: | Francois Le Moigne, Maryvonne Le Plouzennec, Rene Dabard |
|---|---|
| Rok vydání: | 1976 |
| Předmět: |
Stereochemistry
Chemistry organic chemicals Organic Chemistry chemistry.chemical_element Manganese Optically active Biochemistry Medicinal chemistry Inorganic Chemistry Metal visual_art Materials Chemistry visual_art.visual_art_medium heterocyclic compounds Physical and Theoretical Chemistry Enantiomer |
| Zdroj: | Journal of Organometallic Chemistry. 122:365-376 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)82398-0 |
| Popis: | The photochemical substitution, by various phosphines or phosphites, of the carbonyl ligands of derivatives of cymantrene has been studied, giving evidence of the effect of the electron density on the metal for mono- or di-substitution. Optically active derivatives which are chiral at manganese have been synthesized and their enantiomeric stability ascertained. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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