Kinetics and Mechanism of Oxidation of D(+)-Sorbose by Chloramine-T

Autor:	R. Sanehi, S. P. Mushran, K. C. Gupta, R. M. Mehrotra
Rok vydání:	1975
Předmět:	chemistry.chemical_compound chemistry Induction period Inorganic chemistry Kinetics Chloramine-T Physical chemistry Hydroxide Substrate (chemistry) Entropy of activation General Chemistry Activation energy Sorbose
Zdroj:	Bulletin of the Chemical Society of Japan. 48:330-332
ISSN:	1348-0634 0009-2673
DOI:	10.1246/bcsj.48.330
Popis:	The kinetics of oxidation of D(+)-sorbose by chloramine-T has been investigated in high alkaline media. The reaction shows a brief induction period after which a first order dependence in both chloramine-T and substrate is followed. The order in hydroxide ion is observed as fractional being 1.3 under the experimental conditions. The values of energy of activation, frequency factor and entropy of activation have been computed as 28.2 kcal mol−1, 2.90×1019 1 mol−1 s−1 and +29.8 e.u. respectively. A plausible mechanism consistent to the experimental result is proposed.
Databáze:	OpenAIRE
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