Study of the Re0.50Rh0.50 products of thermobaric treatment

Autor:	S. A. Gromilov, I. B. Kireenko, K. V. Yusenko, Alexander P. Tyutyunnik, Yu. G. Zainulin, T. V. D'yachkova
Rok vydání:	2009
Předmět:	Chemistry Scattering Thermal decomposition Analytical chemistry chemistry.chemical_element Rhenium Decomposition Nanocrystalline material Inorganic Chemistry Crystallography Phase (matter) Metastability Materials Chemistry Particle Physical and Theoretical Chemistry
Zdroj:	Journal of Structural Chemistry. 50:306-311
ISSN:	1573-8779 0022-4766
DOI:	10.1007/s10947-009-0042-y
Popis:	The products of thermobaric treatment of the metastable Re0.50Rh0.50 nanocrystalline phase (a= 2.733(2) A, c = 4.364(4) A, space group P63/mmc, CSR ∼5 nm) in a high-pressure chamber were studied. Storage of the phase at 2000°C and 1.5 GPa for 3 min led to the formation of a fused particle (O∼1 mm). The initial composition did not change, but the coherent scattering region (CSR) increased to 52 nm. An increase to 4 GPa in pressure also did not lead to a decomposition of the metastable Re0.50Rh0.50 phase, the unit cell parameters remained the same, and the size of the CSR increased by a factor of four.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bcec64af86a842f56fab37d62a3f31aa https://doi.org/10.1007/s10947-009-0042-y Zobrazit plný text záznamu Plný text ve formátu PDF