A Convenient Synthesis of ω-Acetylenic Acids

Autor:	W. J. Dejarlais, E. A. Emken
Rok vydání:	1980
Předmět:	Dilithium chemistry.chemical_compound Chemistry Organic Chemistry Organic chemistry Alkylation Sodium salt
Zdroj:	Synthetic Communications. 10:653-660
ISSN:	1532-2432 0039-7911
DOI:	10.1080/00397918008065646
Popis:	ω-Acetylenic acids are valuable intermediates in the synthesis of long-chain acids. Their dimagnesium salts may be alkylated with 1-bromo-2-alkynes or 2-alkenes to synthesize many important naturally occurring fatty acids1–3. Also, internally-monounsaturated acids are prepared by alkylation of ω-acetylenic acid dilithium salts4,5 or the sodium salts of their N,N-dimethylamides6.
Databáze:	OpenAIRE
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