Facile Synthesis of Boron Organic Polymers for Efficient Removal and Separation of Methylene Blue, Rhodamine B, and Rhodamine 6G
| Autor: | Changjun Xiang, Xue Zhao, Haibo Zhang, Dan Wang, Xiaohai Zhou, Fulin Zhang, Luchang Liu |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Aqueous solution Renewable Energy Sustainability and the Environment General Chemical Engineering Cationic polymerization chemistry.chemical_element 02 engineering and technology General Chemistry Polymer 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Rhodamine 6G chemistry.chemical_compound Adsorption chemistry Rhodamine B Environmental Chemistry 0210 nano-technology Boron Methylene blue Nuclear chemistry |
| Zdroj: | ACS Sustainable Chemistry & Engineering. 6:16777-16787 |
| ISSN: | 2168-0485 |
| DOI: | 10.1021/acssuschemeng.8b04049 |
| Popis: | Dodecahydro-closo-dodecaborate anion (B12H122–) organic polymers (BOPs) were facilely obtained from aqueous solution via a simple and effective method. Single crystal X-ray diffraction results insinuated that the BOPs were formed by intermolecular forces between 4,4′-bipyridine and B12H122–. The presence of B12H122– gave the BOPs a certain degree of electronegativity, which possessed excellent stability and high adsorption capacity toward the cationic dyes methylene blue (MB), rhodamine B (RB), and rhodamine 6G (RB6G). The adsorption capacity of BOPs for MB, RB, and RB 6G dyes reached 3250 mg·g–1, 1388 mg·g–1, and 2033 mg·g–1, respectively. Through adsorption kinetics and adsorption isotherm results, BOPs exhibited rapid kinetic adsorption and ultrahigh adsorption capacity. Moreover, the BOPs materials could separate MB/MO, MB/RB, MB/RB6G, RB/MO, and RB6G/MO mixed components efficiently by adjusting the pH of the dye solution. It was worth mentioning that BOPs adsorbents could be easily and rapidly regene... |
| Databáze: | OpenAIRE |
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