Synthesis and transformations of perfluoro-2-methyl-3-azido-2-pentene

Autor:	Yurii V. Gatilov, Georgii G. Furin, Irina Yu. Bagryanskay, Eduard L. Zhuzhgov
Rok vydání:	2001
Předmět:	Inorganic Chemistry chemistry.chemical_compound Trifluoromethyl Nucleophilic addition chemistry Pentene Organic Chemistry Environmental Chemistry Physical and Theoretical Chemistry Acetonitrile Biochemistry Medicinal chemistry
Zdroj:	Journal of Fluorine Chemistry. 110:21-24
ISSN:	0022-1139
DOI:	10.1016/s0022-1139(01)00395-5
Popis:	Reactions between perfluoro-2-methyl-2-pentene and NaN3 in acetonitrile at −20°C provided perfluoro-2-methyl-3-azido-2-pentene stable only to 0°C, which decomposed in CCl4 at 20°C to give 2,2-bis(trifluoromethyl)-3-pentafluoroethylaziridine or in EtOH at 20°C to 4,4-bis(trifluoromethyl)-5-ethoxy-5-pentafluoroethyl-1,2,3-triazoline, whose structure was confirmed by the X-ray crystallographic analysis. The routes of formation for these products have been discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bcdd3126ef50b387208b952184e1a8fb https://doi.org/10.1016/s0022-1139(01)00395-5 Zobrazit plný text záznamu Full Text from ScienceDirect