Autoionization reaction of phosgene (OCC12) studied by electron paramagnetic resonance/spin trapping techniques

Autor:	Richard R. Stotts, Felix Feliciano, Susan R. Millette, Carmen M. Arroyo, Jill R. Keeler, Dana L. Kolb
Rok vydání:	1993
Předmět:	Spin trapping Quantitative Biology::Tissues and Organs Toxicology Photochemistry law.invention chemistry.chemical_compound Hyperfine coupling chemistry Autoionization law Spin trap Physics::Atomic Physics Phosgene Electron paramagnetic resonance
Zdroj:	Journal of Biochemical Toxicology. 8:107-110
ISSN:	1522-7146 0887-2082
Popis:	The reaction of phosgene with ni-trone spin traps was investigated using electron paramagnetic resonance (EPR)/spin trapping techniques. Evidence for the intermediacy of a carba-moyl monochloride intermediate was obtained. Isotopic substitution of 13C-phosgene was employed to verify the hyperfine coupling constant assignments. The implications of these observations on pulmonary damage caused by inhalation of phosgene are mentioned.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bcd71a7bb285db819f399ae9e963431b https://doi.org/10.1002/jbt.2570080208 Zobrazit plný text záznamu Plný text