A novel salt-free ruthenium-catalyzed alkylation of aryl amines

Autor:	Matthias Beller, Rinke Altink, Sebastian Bähn, Dirk Hollmann, Rudy F. Parton, Annegret Tillack
Rok vydání:	2008
Předmět:	Shvo catalyst Aryl Organic Chemistry Borrowing hydrogen chemistry.chemical_element Alkylation Biochemistry Medicinal chemistry Pyrrolidine Catalysis Ruthenium chemistry.chemical_compound chemistry Drug Discovery Organic chemistry Amination
Zdroj:	Tetrahedron Letters. 49:5742-5745
ISSN:	0040-4039
Popis:	The alkylation of aryl amines using cyclic amines such as pyrrolidine proceeds via borrowing hydrogen methodology in the presence of 1 mol % Shvo catalyst. During the reaction multiple carbon–nitrogen cleavage and formation occurred. This novel reaction sequence leads to N -aryl-pyrrolidines and -piperidines.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bca260870c89d16aafc98ece4542fab3 https://doi.org/10.1016/j.tetlet.2008.07.107 Zobrazit plný text záznamu Full Text from ScienceDirect