Basicity and ?-electron structure of flavones

Autor:	Konstantin B. Petrushenko, Yu. L. Frolov, F. S. Lur'e, Yu. M. Sapozhnikov
Rok vydání:	1977
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Chemistry Stereochemistry chemistry.chemical_element Protonation General Chemistry Electron Oxygen Flavones Carbonyl group Medicinal chemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 26:1750-1752
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00925194
Popis:	1. The basicity of flavone, its 5- and 4′-methoxy, and its 7- and 4′-hydroxy derivatives changes synonymously with the change in the energy of the π-electron system during protonation. 2. The dihydroxy derivatives (with the exception of 3,5-hydroxyflavone), and also 3-hydroxy- and 3-methoxyflavone, form an intrinsic family of points that are linked by a similar relationship. 3. The existence of a relationship between the basicity of the compounds and the calculated π-electron density on the oxygen of the carbonyl group was not detected.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bc9fde7be0259cca78a1ff981504e25b https://doi.org/10.1007/bf00925194 Zobrazit plný text záznamu Full text from SpringerLink