New stable germylenes, stannylenes, and related compounds

Autor:	Nikolay N. Zemlyansky, Victor N. Khrustalev, Valery V Lunin, Irina V. Borisova, Mikhail S. Nechaev, Mikhail Yu. Antipin, Yuri A. Ustynyuk, Ivan A. Portnyagin
Rok vydání:	2005
Předmět:	Dimer Organic Chemistry Intermolecular force chemistry.chemical_element Germanium Crystal structure Biochemistry Inorganic Chemistry chemistry.chemical_compound Crystallography Monomer chemistry Intramolecular force Materials Chemistry Physical and Theoretical Chemistry X ray analysis Tin
Zdroj:	Journal of Organometallic Chemistry. 690:1172-1177
ISSN:	0022-328X
DOI:	10.1016/j.jorganchem.2004.11.024
Popis:	New stable heteroleptic germanium(II) and tin(II) compounds [(SiMe3)2N-E14-OCH2CH2NMe2]n (E14 = Ge, n = 1 (1), Sn, n = 2 (2)) have been synthesized and their crystal structures have been determined by X-ray diffraction analysis. While compound 1 is monomer stabilized by intramolecular Ge ← N coordination, compound 2 is associated to dimer via intermolecular dative Sn ← O interactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bc7c69390fc6b1913fdc44d625a84e80 https://doi.org/10.1016/j.jorganchem.2004.11.024 Zobrazit plný text záznamu Full Text from ScienceDirect