Volatile barium β-diketonates for use as MOCVD precursors
| Autor: | S. B. Turnipseed, L. Huang, Anthony F. Lagalante, Robert E. Sievers |
|---|---|
| Rok vydání: | 1993 |
| Předmět: |
Diketone
digestive oral and skin physiology Inorganic chemistry chemistry.chemical_element Barium Chemical vapor deposition digestive system diseases Inorganic Chemistry Thermogravimetry chemistry.chemical_compound Monomer chemistry otorhinolaryngologic diseases Materials Chemistry Chelation Physical and Theoretical Chemistry Thin film Volatility (chemistry) |
| Zdroj: | Coordination Chemistry Reviews. 128:285-291 |
| ISSN: | 0010-8545 |
| DOI: | 10.1016/0010-8545(93)80035-4 |
| Popis: | Metal-organic chemical vapor deposition (MOCVD) techniques have been used to deposit thin superconducting films of YBa2Cu3O7-x. A limitation of the technique lies in the volatility of the barium(II) precursors. A review of attempts to enhance volatility through substitution of fluorinated chelating agents and studies to limit oligomerization of the barium chelates are reviewed. Within the past five years, substantial progress has been made in synthesizing more volatile barium complexes, and the most volatile barium compound yet reported is a monomeric chelate in which five hexafluoroacetylacetonato ligands are bonded to barium(II). |
| Databáze: | OpenAIRE |
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