Phosphorylation ofN-Silylpyrroles with Phosphorus Tribromide

Autor: Aleksandr M. Pinchuk, Yurii V. Dmytriv, Andrei A. Tolmachev, Aleksandra A. Chaikovskaya
Rok vydání: 2008
Předmět:
Zdroj: Heteroatom Chemistry. 19:93-96
ISSN: 1098-1071
1042-7163
Popis: Phosphorylation of N-trimethylsilyl- and N-dimethyl-tert-butylsilylpyrroles with phosphorus tribromide in pyridine proceeds selectively at position 3 of the pyrrole ring. Removal of the trialkylsilyl protecting group has furnished the first representatives of N-unsubstituted 3-phosphorylated pyrroles. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:93–96, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20416
Databáze: OpenAIRE