Binuclear and polynuclear transition metal complexes with macrocyclic ligands 7. Directed step-by-step synthesis of novel unsymmetric macrocyclic ligands

Autor:	Nataliya E. Borisova, Marina D. Reshetova, V. V. Roznyatovsky, A. G. Buyanovskaya, Yu. A. Ustynyuk
Rok vydání:	2005
Předmět:	chemistry.chemical_classification Sulfide General Chemistry chemistry.chemical_compound chemistry Transition metal Furan Polymer chemistry Pyridine Mass spectrum Organic chemistry Phenol Methanol Pyrrole
Zdroj:	Russian Chemical Bulletin. 54:2219-2223
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-006-0100-y
Popis:	Novel asymmetric macrocyclic Schiff bases were synthesized by the condensation of N,N′-bis(2-aminophenyl)-3,4-diphenylthiophene-2,5-dicarboxamide (1) with diformyl derivatives of phenol, furan, difurans, pyridine, pyrrole, and dipyrroles. The reaction proceeds in high yields and without by-products in methanol in the presence of inorganic and organic acids (proton-template condensation). In the case of monocyclic diformyl derivatives and di(5-formylfuran-2-yl) sulfide, the reaction occurs in 1,4-dioxane (templateless synthesis). The synthesized macrocycles were characterized by elemental analysis data and NMR and mass spectra.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bc47eea7a78ef082b5f193288e03d0bc https://doi.org/10.1007/s11172-006-0100-y Zobrazit plný text záznamu Full text from SpringerLink