Ferro- and ferri-magnetism in oximato-bridged MIIICuIIchains (M = Mn and Fe). A molecular based ferromagnet with Tc= 9 K: [MnIIICuII-bis(1,2-cyclohexanedioneoximato)(acetato)(H2O)2]

Autor: Beatriz Cervera, Michel Verdaguer, Isabel Castro, Juan Faus, Francesc Lloret, Jean Christophe Colin, Miguel Julve, José Antonio Real, Fernando Sapiña, Yves Journaux, Rafael Ruiz
Rok vydání: 1994
Předmět:
Zdroj: J. Chem. Soc., Chem. Commun.. :2615-2616
ISSN: 0022-4936
DOI: 10.1039/c39940002615
Popis: The study of the magnetic properties of the compounds [MIIICuII(L)2(MeCO2)(H2O)2], M = Mn and L = dimethylglyoximato (dmg)1 or 1,2-cyclohexanedioneoximato (chd)2 and M = Fe and L = dmg 3, shows that 1 is a metamagnetic compound, 2 is a bulk ferromagnet with Tc= 9 K and 3 orders antiferromagnetically at 7.5 K.
Databáze: OpenAIRE