Synthesis of Dithioacetals through Iodine-Promoted Insertion Reactions of Vinylsilane to Disulfides and its Application to Diselenoacetalization
| Autor: | Norio Sakai, Kurumi Fukuda, Yohei Ogiwara, Kento Ishida |
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| Rok vydání: | 2023 |
| Předmět: | |
| Zdroj: | Synthesis. 55:1915-1921 |
| ISSN: | 1437-210X 0039-7881 |
| Popis: | Described herein is an iodide-promoted insertion reaction of vinyltrimethylsilane into diaryl or dialkyl disulfides in the presence of iodine/KF leading to the production of a 1,1′-adduct, a dithioacetal derivative. This method also accomplishes insertion into a diaryl diselenide to afford the corresponding diselenoacetal derivative. |
| Databáze: | OpenAIRE |
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