Synthesis, structures and magnetic properties of dissymmetrical Schiff-base copper(II) complexes: [(Cu2L)2(H2O)4]·(CuL)2·4H2O and [Cu2L(dca)]n

Autor:	Bao-Lin Liu, Ruo-Jie Tao, A-Hui Li, Jie Zhang
Rok vydání:	2013
Předmět:	Schiff base chemistry.chemical_element Crystal structure Atmospheric temperature range Copper Inorganic Chemistry Crystal chemistry.chemical_compound Crystallography chemistry Elemental analysis Materials Chemistry Molecule Physical and Theoretical Chemistry Dicyanamide
Zdroj:	Inorganic Chemistry Communications. 35:333-336
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2013.07.010
Popis:	Two new dissymmetrical Schiff-base copper(II) complexes, [(Cu2L)2(H2O)4]·(CuL)2·4H2O (1) and [Cu2L(dca)]n (2) (H3L = 1-(2-hydroxybenzamido)-2-(2-hydroxy-3-methoxybenzylideneamino)ethane), have been synthesized and characterized by IR, elemental analysis, X-ray crystal diffraction and magnetic properties. Single-crystal structural analysis shows that complex 1 contains a tetranuclear [Cu4L2(H2O)4]2 + cation, two [CuL]− anions and four uncoordinated water molecules. Complex 2 is an infinite two-dimensional network structure in which the tetranuclear [Cu4L2] cations are interlinked by dicyanamide (dca−) bridges in the end-to-end (μ1,5) fashion. The magnetic properties of two complexes have been determined in the temperature range of 2.7–300 K.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bbfde1955dedda1642a0f80ad63d05e2 https://doi.org/10.1016/j.inoche.2013.07.010 Zobrazit plný text záznamu Full Text from ScienceDirect