Water gas shift reaction in the presence of palladium complexes with diphenyl-m-sulfophenylphosphine
| Autor: | Yu. G. Noskov, G. N. Menchikova, A. P. Bezruchenko, E. G. Chepaikin |
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| Rok vydání: | 2019 |
| Předmět: |
inorganic chemicals
010405 organic chemistry Inorganic chemistry chemistry.chemical_element Halide General Chemistry 010402 general chemistry 01 natural sciences Water-gas shift reaction 0104 chemical sciences Catalysis Reaction rate chemistry.chemical_compound Acetic acid chemistry Bromide Hydrobromic acid Palladium |
| Zdroj: | Russian Chemical Bulletin. 68:493-499 |
| ISSN: | 1573-9171 1066-5285 |
| DOI: | 10.1007/s11172-019-2444-0 |
| Popis: | A homogeneous catalytic system containing palladium(ii) halides, diphenyl-m-sulfo-phenylphosphine (or palladium halide complexes with diphenyl-m-sulfophenylphosphine) and hydrohalic acid was developed and studied in the liquid-phase water gas shift reaction. The system based on palladium bromide and hydrobromic acid in aqueous acetic acid (20–40 vol.%) showed the highest activity. The dependences of the initial reaction rate on the concentrations of reagents and catalyst components were studied, a mechanism for the process was proposed, and a kinetic model was developed and found to agree well with experimental results. |
| Databáze: | OpenAIRE |
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