A direct synthesis of 1,3-bis(bromomagnesio)propane

Autor:	F.M. Bickelhaupt, Otto S. Akkerman, C. Blomberg, J. W. F. L. Seetz, H.P. Böhm, F.A. Hartog
Rok vydání:	1982
Předmět:	chemistry.chemical_compound Allylmagnesium bromide chemistry Propane Magnesium Organic Chemistry Drug Discovery chemistry.chemical_element Organic chemistry Biochemistry Decomposition
Zdroj:	Tetrahedron Letters. 23:1497-1500
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)87142-7
Popis:	Careful addition of 1,3-dibromopropane to magnesium in Et 2 O yields 1,3-bis(bromomagnesio)propane which is purified via “magnesacyclobutane” . Reactions of with H 2 O, CO 2 , HgBr 2 and Me 3 SnCl are reported. MgBr 2 catalyses the decomposition of to allylmagnesium bromide .
Databáze:	OpenAIRE
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