Unveiling micro internal short circuit mechanism in a 60 Ah high-energy-density Li-ion pouch cell
| Autor: | Wu Shuaijin, Fengling Yun, Quan Wei, Changhong Wang, Liu Bingxue, Qiang Zhang, Liu Shiyang, Wang Jiantao, Qi Xiaopeng, Sheng Fang, Wang Rennian, Kieran Doyle-Davis, Bin Li, Xueliang Sun, Yi Cui, Xing Chaojian, Pang Jing |
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| Rok vydání: | 2021 |
| Předmět: |
Materials science
Thermal runaway Renewable Energy Sustainability and the Environment business.industry fungi Volt 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology digestive system 01 natural sciences Cathode 0104 chemical sciences Ion law.invention Anode law Electrode Optoelectronics General Materials Science Electrical and Electronic Engineering 0210 nano-technology business Short circuit Voltage |
| Zdroj: | Nano Energy. 84:105908 |
| ISSN: | 2211-2855 |
| Popis: | The identification, evaluation, and prevention of micro internal short circuits (ISCs) are crucial for the safety of large-capacity high-energy-density (HED) Li-ion cells. However, the evolution mechanism and the premonitory signals of the micro ISCs are not yet completely understood. Via a high-precision penetration test and accelerating rate calorimetry, we successfully trigger and investigate on-demand ISCs on a 60 Ah HED (≥ 290 Wh kg–1) Li-ion pouch cell with Si-based anode/Ni-rich cathode couple. Detailed behaviors of the cell components during micro ISCs, such as pinhole and crack formation, pore-closing, and rupture of the separators, as well as the destruction of positive electrodes and fusion of Al current collectors, are observed. Moreover, the correlation of these internal effects with external cell signals is identified. We demonstrate that voltage change signals, even at millivolt level, are noteworthy and can be used as premonitory signals for early warning of micro ISCs and leading indicators for predicting cell thermal runaway. The disclosed micro ISC propagation, alleviation, and acceleration mechanisms could guide the design of safe HED Li-ion cells. |
| Databáze: | OpenAIRE |
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