| Popis: |
The article considers the interaction of Ti(IV) with 2, 3, 4-trihydroxy-3'-fluoroazobenzene (H3R) in the presence and absence of phenontroline (Phen), α, α'-dipyridine (α, α'-dip), and batophenontroline (B-phen) studied by using a spectrophotometric method. It has been found that the yield of the binary complex is maximum at pHopt = 5 (λmax = 428 nm), and for mixed-ligand complexes, pHopt = 3.0; 4.0; 3.5; λmax = 477 nm, 443 nm, 440 nm Ti(OH)2(H2R)-Phen, Ti (OH)2(H2R)-α, α'-dip and Ti(OH)2(H2R)-B-phen, respectively. It has been investigated that a twofold excess of the reagent is required for complete binding of titanium(IV) into the complex. The influence of time and temperature on the complexation is investigated. The stability constants of binary and mixed-ligand titanium(IV) complexes were calculated: logβ = 8.61 ± 0.05 for Ti(OH)2(H2R)2, logβ = 10.98 ± 0.06 for Ti(OH)2(H2R)-Phen, logβ = 10.85 ± 0.04 for Ti (OH)2(H2R)-α, α'-dip, logβ = 11.26 ± 0.03 for Ti(OH)2(H2R)-B-phen. The ratio of the reacting components in the binary complex is 1 : 2, and in the mixed ligands 1 : 2 : 2. The influence of foreign ions and masking substances on the titanium(IV) complexation with reagents has been studied. The determination is practically not interfered by alkaline, alkaline-earth and some transition elements. Due to these characteristics, the complexes can be used for defining titanium(IV) in different objects. |
