Tetrazole-bridged manganese coordination polymer as high-energy material
| Autor: | Yoel Friedman, Israel Goldberg |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Coordination polymer
Solvothermal synthesis Inorganic chemistry Detonation chemistry.chemical_element 02 engineering and technology Crystal structure Manganese 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Metal-organic framework Tetrazole Thermal stability Physical and Theoretical Chemistry 0210 nano-technology |
| Zdroj: | Polyhedron. 139:327-330 |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/j.poly.2017.11.010 |
| Popis: | Metal organic frameworks (MOFs) containing nitrogen-rich organic linkers and light-metal ions which exhibit remarkable thermal stability and shock resistivity, can be considered as potential high energetic materials. This work presents a three-dimensional framework MOF structure with manganese and sodium ions as the connecting nodes and N,N-bis(tetrazol-5-yl)amine (bta) di-anionic ligands as the organic linker, generated in-situ through solvothermal synthesis. This solid is considerably robust, and it shows attractive energetic performance as estimated by sensitivity tests and semi-empirical calculations of its detonation properties. |
| Databáze: | OpenAIRE |
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