Synthesis and characterization of cobalt(II) complexes with triethanolamine and succinate and/or nitrate anions
| Autor: | Yulia A. Kondratenko, T. A. Kochina, Igor S. Ignatyev, V. Fundamensky |
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| Rok vydání: | 2017 |
| Předmět: |
010405 organic chemistry
Metals and Alloys Cationic polymerization chemistry.chemical_element 010402 general chemistry 01 natural sciences 0104 chemical sciences Catalysis Inorganic Chemistry chemistry.chemical_compound chemistry Nitrate Triethanolamine Polymer chemistry Materials Chemistry medicine Cobalt Organometallic chemistry medicine.drug |
| Zdroj: | Transition Metal Chemistry. 43:127-136 |
| ISSN: | 1572-901X 0340-4285 |
| DOI: | 10.1007/s11243-017-0199-8 |
| Popis: | Three Co(II) complexes of triethanolamine (TEA) namely [Co(N(CH2CH2OH)3)2](NO3)2 (1), [Co(N(CH2CH2OH)3)2](OOC(CH2)2COO) (2) and [Co2(N(CH2CH2OH)3)2(NO3)2(OOC(CH2)2COO)] (3) were synthesized and characterized by physicochemical and spectroscopic methods. The first two complexes are cationic and are formed by Co2+ cations coordinated by two TEA ligands plus nitrate or succinate anions, respectively. The equilibrium geometries of the [Co(TEA)2]2+ cations have been optimized at the B3LYP/cc-pVDZ level. Complex 3 is a product of the reaction between cationic complexes 1 and 2. |
| Databáze: | OpenAIRE |
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