Reactivity of micelle-forming 1-alkyl-3(1-oximinoethyl)pyridinium bromides in acyl group transfer reactions

Autor:	K. K. Tuchinskaya, Anatolii F. Popov, A. E. Shumeiko, I. A. Belousova, T. M. Prokop’eva, I. V. Kapitanov, M. L. Kostrikin, N. G. Razumova, M. K. Turovskaya
Rok vydání:	2011
Předmět:	chemistry.chemical_classification General Chemistry Cleavage (embryo) Medicinal chemistry Micelle chemistry.chemical_compound chemistry Nucleophile Organic chemistry lipids (amino acids peptides and proteins) Reactivity (chemistry) Pyridinium Alkyl Acyl group
Zdroj:	Theoretical and Experimental Chemistry. 47:21-29
ISSN:	1573-935X 0040-5760
DOI:	10.1007/s11237-011-9179-9
Popis:	The reactivity of a series of micelle-forming 1-alkyl-3-(1-oximinoethyl)pyridinium bromides in the cleavage of typical acyl substrates was studied and analyzed. The nucleophilicity of the functional surfactants does not change significantly upon variation of the length of the alkyl chain. The differences in the observed rates of cleavage of the model substrates are attributed to differences in the hydrophobic properties of the surfactants.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bbb4f26dca6bb73e41b1f38e9cfd3f0e https://doi.org/10.1007/s11237-011-9179-9 Zobrazit plný text záznamu Plný text ve formátu PDF