| Autor: |
A. Priwitzer, H.J. Frohn |
| Rok vydání: |
1991 |
| Předmět: |
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| Zdroj: |
Journal of Fluorine Chemistry. 54:322 |
| ISSN: |
0022-1139 |
| DOI: |
10.1016/s0022-1139(00)83831-2 |
| Popis: |
Besides IF 3 no binary iodine(III) oxide or ternary iodine(III) fluoride oxide is known. Now we report on the preparation of an organoiodine(III) fluoride oxide: C 6 F 5 I(F)OI(F)C 6 F 5 ( I ). I is prepared by well-aimed fluorine-oxygen — metathesis on C 6 F 5 IF 2 . Another new class of iodine(III) compounds are salts with the aryliodine(III)fluoride cation [ RIF ] + ( II ). The cation II is also obtained from aryliodine(III)difluorides. It has got a strong electrophilic character and allows e.g. electrophilic substitution-reactions on aromatic compounds under formation of asymmetric diaryliodonium-cations: With hard bases II reacted spontaneously, e.g. with F − the neutral educt molecule RIF 2 is obtained. Furthermore we report an alternative method to the already known preparative routes for C 6 F 5 IF 2 . The advantage of the new way is the purity of the product. For the first time a correct melting-point and decomposition-temperature for C 6 F 5 IF 2 is reported. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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