ChemInform Abstract: Photocatalytic Aminodecarboxylation of Carboxylic Acids

Autor:	Kaitie C. Cartwright, Simon B. Lang, Theresa M. Locascio, Jon A. Tunge, Richard Welter
Rok vydání:	2016
Předmět:	chemistry.chemical_classification chemistry.chemical_compound chemistry Electrophile Photocatalysis Diazo General Medicine Combinatorial chemistry Alkyl
Zdroj:	ChemInform. 47
ISSN:	0931-7597
DOI:	10.1002/chin.201648061
Popis:	Aminodecarboxylation of unactivated alkyl carboxylic acids has been accomplished utilizing an organic photocatalyst. This operationally simple reaction utilizes readily available carboxylic acids to chemoselectively generate reactive alkyl intermediates that are not accessible via conventional two-electron pathways. The organic radical intermediates are efficiently trapped with electrophilic diazo compounds to provide aminated alkanes.
Databáze:	OpenAIRE
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