ChemInform Abstract: New Stereoselective Transformations Involving Organoboranes and Organozinc Compounds. Applications of the Boron-Zinc Chain Reaction and the Diastereoselective Migration of Organoboranes

Autor:	Paul Knochel, Hamid Laaziri, Lars O. Bromm, Frederic Lhermitte, Jesús A. Varela, Andreas Boudier, Kolja M. Knapp, Eike Hupe
Rok vydání:	2010
Předmět:	inorganic chemicals Chemistry Reagent Organic chemistry chemistry.chemical_element Molecule Stereoselectivity General Medicine Zinc Boron Chain reaction
Zdroj:	ChemInform. 32
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200144267
Popis:	The boron-zinc exchange is an unique way for preparing chiral secondary alkylzinc reagents which are configurationally stable over a wide temperature scale. Coupled with the thermal rearrangement of tertiary organoboranes, a broad range of open-chain and cyclic polyfunctional molecules have been prepared. In addition, several examples of a diastereoselective remote C-H activation have been studied.
Databáze:	OpenAIRE
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