Stabilization of an anionic guest adsorbed on sodium faujasites through enhanced Coulombic interaction

Autor:	Hermenegildo García, Jordi Marquet, José Luis Bourdelande, José Raúl Herance
Rok vydání:	2004
Předmět:	Sodium Inorganic chemistry General Physics and Astronomy chemistry.chemical_element Reaction intermediate Alkali metal Photochemistry Meisenheimer complex Adduct Adsorption chemistry X-ray photoelectron spectroscopy Physical and Theoretical Chemistry Zeolite
Zdroj:	Chemical Physics Letters. 395:49-52
ISSN:	0009-2614
DOI:	10.1016/j.cplett.2004.07.048
Popis:	The negatively charged adduct formed by reaction of 2,4-dinitroaniline with NaBH4 (Meisenheimer complex) has been successfully incorporated inside faujasites. The internal location of the anionic Meisenheimer guest was confirmed by XPS. This anionic reaction intermediate becomes largely stabilized by the inclusion in zeolite as the result of an increase of the association constant with alkali metal ions inside the zeolite cavities.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bb69716ab89367ea06cf28645a1bbea4 https://doi.org/10.1016/j.cplett.2004.07.048 Zobrazit plný text záznamu Full Text from ScienceDirect