A sulphur and uranium fiesta! Synthesis, structure, and characterization of neutral terminal uranium(vi ) monosulphide, uranium(vi ) η2-disulphide, and uranium(iv ) phosphine sulphide complexes
| Autor: | David E. Morris, Justin K. Pagano, Carol J. Burns, Jaqueline L. Kiplinger, David S. J. Arney, Brian L. Scott |
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| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Double bond 010405 organic chemistry Chemistry Ligand Solid-state chemistry.chemical_element Uranium 010402 general chemistry 01 natural sciences Sulfur 0104 chemical sciences Adduct Inorganic Chemistry chemistry.chemical_compound Crystallography Cyclic voltammetry Phosphine |
| Zdroj: | Dalton Transactions. 48:50-57 |
| ISSN: | 1477-9234 1477-9226 |
| DOI: | 10.1039/c8dt02932f |
| Popis: | Three new uranium species (C5Me5)2U([double bond, length as m-dash]N-2,6-iPr2-C6H3)([double bond, length as m-dash]S), (C5Me5)2U([double bond, length as m-dash]N-2,6-iPr2-C6H3)(η2-S2), and (C5Me5)2U([double bond, length as m-dash]N-2,6-iPr2-C6H3)(S[double bond, length as m-dash]PMe3) were synthesized and fully characterized by a combination of NMR, IR, and UV/vis-NIR spectroscopies, elemental analysis, and cyclic voltammetry. The solid state structures of (C5Me5)2U([double bond, length as m-dash]N-2,6-iPr2-C6H3)([double bond, length as m-dash]S) and (C5Me5)2U([double bond, length as m-dash]N-2,6-iPr2-C6H3)(η2-S2) were also determined. The compound (C5Me5)2U([double bond, length as m-dash]N-2,6-iPr2-C6H3)([double bond, length as m-dash]S) is the first neutral uranium complex with a terminal sulphido ligand, and (C5Me5)2U([double bond, length as m-dash]N-2,6-iPr2-C6H3)(S[double bond, length as m-dash]PMe3) is the first uranium compound with a coordinated phosphine sulphide ligand. The phosphine sulphide adduct, (C5Me5)2U([double bond, length as m-dash]N-2,6-iPr2-C6H3)(S[double bond, length as m-dash]PMe3), can be synthesized either by reaction of the uranium(iv) complex (C5Me5)2U([double bond, length as m-dash]N-2,6-iPr2-C6H3)(thf) with S[double bond, length as m-dash]PMe3 or by the reaction of the uranium(vi) terminal sulphido complex (C5Me5)2U([double bond, length as m-dash]N-2,6-iPr2-C6H3)([double bond, length as m-dash]S) with PMe3. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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