Intermolecular Interaction in Rubber Solutions

Autor: V. A. Berestnev, V. E. Gul
Rok vydání: 1959
Předmět:
Zdroj: Rubber Chemistry and Technology. 32:668-672
ISSN: 1943-4804
0035-9475
DOI: 10.5254/1.3542433
Popis: A study has been made of the viscosities of butadiene acrylonitrile rubber solutions and of the equilibrium swelling of vulcanizates of these rubbers with the same degree of crosslinking, in various solvents. It was found that the viscosity and light scattering characteristics of the solutions, and swelling of the vulcanizates of butadiene acrylonitrile rubbers are not steady functions of the degree of intermolecular interaction, represented by the difference of the square roots of the cohesive energy densities of the polymer and the solvent but pass through a maximum with variations in the polarity of the rubber.
Databáze: OpenAIRE