Structure and morphology controllable synthesis of Ag/carbon hybrid with ionic liquid as soft-template and their catalytic properties
| Autor: | Boxuan Li, Yun Sheng Ding, Xiaomin Zhang, Shuying Wu, Long Chen, Hai Ou Tang |
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| Rok vydání: | 2008 |
| Předmět: |
Chemistry
Analytical chemistry Infrared spectroscopy Nanoparticle Condensed Matter Physics Electronic Optical and Magnetic Materials Catalysis Inorganic Chemistry chemistry.chemical_compound symbols.namesake Template reaction Silver nitrate Chemical engineering Ionic liquid Materials Chemistry Ceramics and Composites symbols Hydrothermal synthesis Physical and Theoretical Chemistry Raman spectroscopy |
| Zdroj: | Journal of Solid State Chemistry. 181:2171-2177 |
| ISSN: | 0022-4596 |
| DOI: | 10.1016/j.jssc.2008.05.006 |
| Popis: | Ag/carbon hybrids were fabricated by the redox of glucose and silver nitrate (AgNO 3 ) in the presence of imidazolium ionic liquid ([C 14 mim]BF 4 ) under hydrothermal condition. Monodisperse carbon hollow sub-microspheres encapsulating Ag nanoparticles and Ag/carbon cables were selectively prepared by varying the concentration of ionic liquid. Other reaction parameters, such as reaction temperature, reaction time and the mole ratio of silver nitrate to glucose, play important roles in controlling the structures of the products. The products were characterized by XRD, TEM (HRTEM), SEM, energy-dispersive X-ray spectroscopy (EDX), FTIR spectroscopy and a Raman spectrometer. The possible formation mechanism was proposed. The catalytic property of the hybrid in the oxidation of 1-butanol by H 2 O 2 was also investigated. |
| Databáze: | OpenAIRE |
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