Antimony-121 MöSsbauer Spectra for Crown Ether Complexes of Antimony(III) Trihalides, SbX3(crown)

Autor:	Masuo Takeda, Kazuyuki Minowa, Atsushi Matsuura, Chikara Fujita, Masashi Takahashi
Rok vydání:	2002
Předmět:	chemistry.chemical_classification Bond length Crystallography chemistry Antimony Inorganic chemistry Intermolecular force Crown (botany) Mössbauer spectroscopy chemistry.chemical_element Weak interaction Lone pair Crown ether
Zdroj:	Hyperfine Interactions (C) ISBN: 9781402010873
Popis:	Antimony-121 Mossbauer spectra for the crown ether complexes of SbX3 (X = Cl, Br, F) are measured at 20 K. The Mossbauer parameters indicate that the stereochemical activity of the lone pair is changed as a result of the weak interaction between SbX3 and crown ether. A good relation between Mossbauer parameters and Sb-O bond length is observed though some intermolecular interactions are important in SbF3 complexes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bb232d4fb37b5dd49c322172fa8fd8ee https://doi.org/10.1007/978-94-010-0281-3_81 Zobrazit plný text záznamu