Catalysis of Organic Reactions by Carbenes and Carbene Complexes

Autor:	V. Sh. Saberov, O. P. Shvaika, Gennady F. Rayenko, Artyom V. Kiselyov, Nataliya V. Glinyanaya, K. A. Marichev, Arthur V. Knishevitsky, Nikolai I. Korotkikh
Rok vydání:	2013
Předmět:	chemistry.chemical_compound chemistry Organic reaction Transition metal carbene complex Organic Chemistry Organic chemistry Halogenation Organic synthesis Transesterification Benzoin condensation Carbene Catalysis
Zdroj:	Chemistry of Heterocyclic Compounds. 49:19-38
ISSN:	1573-8353 0009-3122
DOI:	10.1007/s10593-013-1230-4
Popis:	In this review, the issues concerning the effectiveness of catalysis by carbenes and their transition metal complexes in a range of organic reactions are discussed as one of the developing areas in contemporary organic chemistry. Among the transformations catalyzed by carbenes, our attention was directed to the transesterification and benzoin condensation reactions that are potentially important for practical application. In the case of transformations catalyzed by the metal carbene complexes, we focussed on the reduction of multiple bonds and the reductive dehalogenation of haloaromatic compounds that are important for organic synthesis and utilization of environmental toxicants.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::bb129f7d563c03d4002d5615c90af97d https://doi.org/10.1007/s10593-013-1230-4 Zobrazit plný text záznamu Plný text ve formátu PDF