Simultaneous binding of soft and hard metals to a pyrimidine nucleobase: Preparation and X-ray structure of [(en)Pd(1-MeT)2Na2](NO3)2·H2O (1-MeT = 1-methylthymine anion)

Autor:	Alberto Albinati, Wolfgang Micklitz, Francesca Lianza, Bernhard Lippert
Rok vydání:	1994
Předmět:	1-methylthymine Pyrimidine Chemistry X-ray Crystal structure Nucleobase Ion Inorganic Chemistry Crystallography chemistry.chemical_compound Materials Chemistry Physical and Theoretical Chemistry Stoichiometry Monoclinic crystal system
Zdroj:	Inorganica Chimica Acta. 227:5-10
ISSN:	0020-1693
DOI:	10.1016/0020-1693(94)04133-4
Popis:	The crystal structure of [(en)Pd(1-MeT)2Na2](NO3)2·H2O, where 1-MeT = 1-methylthymine anion, C6H7N2O2, is reported. The compound crystallizes in the monoclinic system, space group P21/c with a = 8.203(1), b = 20.908(5), c = 13.644(5) A, β = 98.35(2)°, V = 2316(2) A3. Pd binding is through N3 of the two 1-MeT rings. The two Na+ are coordinated to two O4 and two O2 oxygens of the 1-MeT rings, respectively. The compound represents the first structurally characterized example of M,M′2 stoichiometry derived from a cis-a2ML2 compound.
Databáze:	OpenAIRE
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