Polymerization of propylene by metallocene and Ziegler-Natta mixed catalytic systems. Study of polypropylene properties
| Autor: | Gershon Lidor, Anatoli Lisovskii, Moris S. Eisen, Michael Shuster, Michael Gishvoliner |
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| Rok vydání: | 1998 |
| Předmět: |
Polypropylene
chemistry.chemical_classification Materials science Polymers and Plastics biology Polymer science Organic Chemistry Polymer Natta biology.organism_classification Catalysis law.invention chemistry.chemical_compound chemistry Polymerization Chemical engineering law Materials Chemistry Crystallization Ziegler–Natta catalyst Metallocene |
| Zdroj: | Journal of Polymer Science Part A: Polymer Chemistry. 36:3063-3072 |
| ISSN: | 1099-0518 0887-624X |
| DOI: | 10.1002/(sici)1099-0518(199812)36:17<3063::aid-pola7>3.0.co;2-2 |
| Popis: | Propylene was polymerized with metallocene and Ziegler-Natta mixed-catalytic systems to obtain reactor blends of metallocene and Ziegler-Natta-derived propylene homopolymers. The two catalytic systems are able to act jointly, providing individual polymers with different melting and crystallization temperatures. Compatibility between the components of the mixed-catalytic systems and the influence of the components on the polymerization process and on the properties of the reactor blends were studied. Thermal, mechanical, viscoelastic, rheological, and optical properties of the blends were tested and compared with those of conventional polypropylene grades. |
| Databáze: | OpenAIRE |
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