Cationization of organic molecules under pulsed laser induced ion generation
Autor: | F. R. Krueger, P. K. D. Feigl, F. Hillenkamp, B. Schueler |
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Rok vydání: | 1981 |
Předmět: | |
Zdroj: | Organic Mass Spectrometry. 16:502-506 |
ISSN: | 1096-9888 0030-493X |
DOI: | 10.1002/oms.1210161107 |
Popis: | Mass spectra of various involatile organic compounds, obtained by surface analysis with a laser microprobe mass analyser are reported. Metal-cationized quasimolecular ions of adenine, adenosine, 5-adenylic acid and sucrose supported on metal foils were observed. Metal attachment can also be detected from mixtures of metal salts and the organic compounds. Silver-cationized sugar molecules and atomic silver ions solvated by (H2O)x and (NH3)x (x = 1,2) have been found. The mass spectra are compared with those obtained by secondary ion mass spectrometry and similar techniques, discussing the processes of ion generation involved. |
Databáze: | OpenAIRE |
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